2-Methyl-4-((phenylthio)methyl)phenol (1a): white solid, m.p: 68-70°C
1H NMR: (CDCl3, 400 MHz): δ 7.31-7.29 (m, 2H), 7.26-7.22 (m, 2H), 7.18-7.14 (m, 1H), 7.04 (s, 1H), 6.98 (d, J = 8.0 Hz, 1H), 6.65 (d, J = 8.0 Hz, 1H), 5.0 (s, 1H), 4.03 (s, 2H), 2.18 (s, 3H).
13C NMR: (CDCl3, 100 MHz): δ 153.1, 136.7, 131.7, 129.6, 129.3, 128.9, 127.6, 126.3, 124.2, 115.1, 38.5, 15.9
IR (CHCl3): 3847, 3350, 3058, 2921, 2850, 2351, 2284, 1600, 1585, 1501, 1479, 1436, 1384, 1368, 1298, 1265, 1245,
1201, 1151, 1114, 1089, 1070, 1042, 1024 cm-1
2-Methyl-4,6-bis((phenylthio)methyl)phenol (1b): light brown solid m.p : 97-99°c
1H NMR: (CDCl3, 400 MHz): δ 7.34-7.31 (m, 2H), 7.27-7.17 (m, 8H), 6.97 (s, 1H), 6.84 (s, 1H), 5.95 (s, 1H), 4.11 (s, 2H), 3.96 (s, 2H), 2.21 (s, 3H).
13C NMR: (CDCl3, 100 MHz): δ 152.2, 136.7, 134.5, 131.0, 130.7, 129.6, 129.0, 128.9, 128.8, 128.7, 127.1, 126.2, 125.4, 122.0, 38.4, 36.0, 15.9.
IR (CHCl3): 3445, 2921, 2852, 1619, 1480, 1438, 1019 cm-1.